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Chemistry
402: Advanced Inorganic Chemistry (2008)
Instructor: |
Dr. C.D. Schaeffer |
Office: |
Musser Hall,
Room 2-104 |
Telephone: |
Ext. 1128 (office)
or 1126 (chemistry secretary) |
E-mail: |
schaeffercd@etown.edu |
Office Hours: |
MTuWThF, 7:00-8:00
a.m., and by appointment |
Class: |
TuTh, 8:00-8:50
a.m., Musser Hall, Room 101 |
Course Prerequisites: Ch 344
Required Textbooks and Materials
J.E. Huheey, E.A. Keiter and R.L. Keiter, “Inorganic
Chemistry: Principles of
Structure & Reactivity,” 4th ed., Harper & Row,
NY, 1994 (ISBN 0-06-042995-X).
A.K. Brisdon, “Inorganic Spectroscopic Methods,” Oxford
University
Press, NY, 1998 (ISBN 0-19-855949-6).
M.J. Winter, “d-Block Chemistry,” Oxford University
Press, NY, 1997 (ISBN 0-19-855696-9).
Supplemental Work
Optional reading is listed at the end of every chapter
of the textbook. Additional problems may be found in the textbook
and in any other inorganic chemistry textbook, many of which may be found
in the chemistry library, room 1-103, Musser Hall.
Objectives
In order to successfully fulfill the objectives of Ch
402, the student must be able to define basic terms, to perform appropriate
calculations, and to demonstrate a mastery of the basic principles of structure,
bonding and reactivity of main group and transition elements. Various
aspects of these areas include, but are not limited to:
1. Molecular geometry and the Gillespie-Nyholm rules
as they apply to the prediction of structures.
2. Acids and bases: theories, applications and
structural correlations.
3. Ionic solids and the application of thermodynamics
to the prediction of stability and other properties.
4. Molecular symmetry and point group predictions.
5. Chemical bonding: theories and applications.
6. Descriptive chemistry of the main group elements.
7. Transition metals: descriptive chemistry, nomenclature,
bonding, and reactivity.
8. Organometallic compounds of the main group and transition
elements: nomenclature, bonding, structure by physical methods,
and reactivity.
Attendance
Regular attendance at lectures is required of all students.
Four or more absences will result in a lowering of your final grade by
one letter. You are responsible for everything that is said during
lectures. Minimal preparation for lectures consists of reading the
assignments (before coming to class) and doing the assigned homework.
Problem and Reading Assignments
Responding to questions and problems in frequent and
serious study sessions can be one of the most effective learning techniques.
Examinations may contain questions similar to those in the homework.
If you delay problem solving and studying until just prior to the quizzes
and examinations, you will be asking for trouble.
Examinations and Quizzes
Two examinations will be given during lecture periods
on the indicated dates. Under no circumstances will these examinations
be rescheduled. Brief quizzes will be given during lecture periods.
The dates and topics of the quizzes may or may not be announced in advance.
A comprehensive final examination will be administered at the end of the
course during the final examination period. Attendance at exams and
quizzes is required; there will be no make-up exams or quizzes under
any circumstances. Unexcused absence from an exam or quiz will be
rewarded with a grade of zero.
Grading
Examinations and quizzes will be graded on a scale of
0-100%. Letter grades corresponding to these percentages are as follows:
0 - 59% = F
60 - 69% = D
70 - 79% = C
80 - 89% = B
90 -100% = A
The final course grade will be derived from the average
of the numerical grades in the exams and quizzes. Other factors,
such as improvement during the semester, will also be considered.
Letter equivalents to the final numerical total follow:
0 - 59% = F |
70 - 72% =
C- |
83 - 86% =
B |
60 - 62% =
D- |
73 - 76% =
C |
87 - 89% =
B+ |
63 - 66% =
D |
77 - 79% =
C+ |
90 - 92% =
A- |
67 - 69% =
D+ |
80 - 82% =
B- |
93 -100% =
A |
Students may request a grade of "I" by submitting a formal
written request to the professor of that course. Grades of "I" are
assigned for extenuating circumstances only. They are not given simply
to allow additional time to complete required course work or to improve
a course grade. Forms are available in the Registration & Records
Office.
Academic Integrity
Students are expected to be familiar with the policy
regarding academic dishonesty and plagiarism as outlined in the College’s
Student Handbook, and in the most recent edition of the pamphlet, “Academic
Integrity at Elizabethtown College.” These activities will not be
tolerated, and will be penalized severely.
Disability Statement
If you have a documented disability and need reasonable
accommodations to fully participate in course activities or meet course
requirements, you must: (1) contact the Director of Disability Services,
Tammie Longsderff, in the Center of Student Success, BSC 226, 717-361-1549,
longsdtl@etown.edu; and (2) meet with me, the course instructor,
with two weeks of receiving a copy of the accommodation letter from Disability
Services to discuss your accommodation needs and their implementation.
Tentative Lecture Outline & Examination Schedule
Chapter &
Topic |
Date |
Introduction to Ch 402; Literature;
Structure of the Atom |
Aug. 26, 28 |
Ionic Solids; Thermochemistry |
Sep. 2, 4, 9 |
Molecular Geometry |
Sep. 9, 11, 16 |
Covalent Bonds |
Sep. 16, 18, 23 |
Solid State; Chemical Forces |
Sep. 25, 30 |
Symmetry; Group Theory |
Oct. 2 |
Exam 1 |
Oct. 7 (Tuesday) |
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Acids and Bases |
Oct. 14, 16, 21, 23 |
Main Group Chemistry; Periodicity |
Oct. 28, 30, Nov. 4, 6, 11 |
Exam 2 |
Nov. 13 (Thursday) |
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Coordination Chemistry 1 |
Nov. 18, 20, 25 |
Coordination Chemistry 2 & 3; Special
Topics (Time Permitting) |
Dec. 2, 4 |
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Final Examination,
Cumulative |
December 9 (Tuesday), 7:30 - 10:30 a.m. |
Reading & Problem Assignment
Topic Assignment
Introduction to Inorganic Chemistry Reading: Ch. 1;
Appendix A & I
Problems: To be assigned
Structure of the Atom Reading: Ch. 2, pps. l0-45
Problems: 2, 3, 6, l0, 14, 16, 20, 23, 24
Symmetry & Group Theory Reading: Ch. 3, pps. 46-85
Problems: Problem set from Dr. Schaeffer
Ionic Compounds Reading: Ch. 4, pps. 92-134
Problems: 3, 9-11, 13, 14, 16, 19, 23, 24, 26,
35
Covalent Bonds Reading: Ch. 5, pps. 138-199
Problems: 1-11, 15, 17, 22
Molecular Geometry Reading: Ch. 6, pps. 203-246
Problems: 1, 2, 4-6, 9, 11, 13, 20, 29, 32
The Solid State Reading: Ch. 7, pps. 252-288
Problems: To be assigned
Chemical Forces Reading: Ch. 8, pps. 290-314
Problems: 5, 7, 10, 11, 13(a, b), 17
Acids & Bases Reading: Ch. 9, pps. 318-355
Problems: 3, 4, 6, 7, 19(a, c, d)
Coordination Chemistry I Reading: Ch. 11, pps. 387-468
Problems: 1-3, 7, 10, 18
Coordination Chemistry II Reading: Ch. 12, pps. 472-531
Problems: 1, 2, 9, 12, 14
Coordination Chemistry III Reading: Ch. 13, pps. 537-572
Problems: To be assigned
Organometallic Chemistry Reading: Ch. 15, pps. 623-730
Problems: 1, 3, 7, 8, 41, 47, 53
Main Group Chemistry Reading: Ch. 17, pps. 824-853
Problems: 1, 3, 4, 6-9, 11, 12, 18
Periodicity Reading: Ch. 18, pps. 857-885
Problems: 3, 6, 7, 10-12, 14, 19
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